Search results for "Equilibrium phase"

Phytoplankton equilibrium phases during thermal stratification in a deep subtropical reservoir

2008

SUMMARY 1. Equilibrium and non-equilibrium hypotheses have often been used to explain observations in community ecology. Published case studies have demonstrated that steady state phytoplankton assemblages are more likely to occur in deep lakes than in shallow mixed ones. 2. Phytoplankton seasonal succession was studied by weekly sampling in Faxinal Reservoir (S Brazil), a subtropical deep, clear, warm monomictic and slightly eutrophic reservoir. This study demonstrated an alternation of steady and non-steady state phases of phytoplankton assemblages with different dominant species during the steady states. 3. During the studied period, three steady states were identified with different dom…

2017

Computer simulations are used to model the phase change that occurs as glasses transition from a liquid phase to a so-called ``ideal glass phase.''

Crystalline Non‐Equilibrium Phase of a Cobalt(II) Complex with Tridentate Ligands

2015

In six-coordinate complexes, flexible tridentate ligands enable mer, cis-fac, and trans-fac stereoisomers. With labile metal ions of the first transition metal series, typically only the final thermodynamic product is available because of the rapid isomerization processes. Here we report on the structural characterization of a so far elusive kinetic intermediate of [Co(ddpd)2](BF4)2 (1; ddpd = N,N′-dimethyl-N,N′-dipyridine-2-yl-pyridine-2,6-diamine). Microcrystals of the cis-fac isomer of 1 were obtained by rapid precipitation. The solid-state structure of cis-fac-1 was determined from electron diffraction data.

GEOMETRY OF DISSIPATIVE PHASE TRANSITIONS

The main objective of this thesis is the development of geometrical methods for the investigation of critical phenomena. In particular, a novel approach based on the Uhlmann curvature is introduced for the investigation of non-equilibrium steady-state quantum phase transitions (NESS-QPTs). Equilibrium phase transitions fall invariably into two markedly non-overlapping categories: classical phase transitions and quantum phase transitions. NESS-QPTs offer a unique arena where such a distinction fades off. We propose a method to reveal and quantitatively assess the quantum character of such critical phenomena. We apply this tool to a paradigmatic class of lattice fermion systems with local res…